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Control of oxidation on NiSix during etching and ashing processes
Authors:S. Sakamori  K. Yonekura  T. Kosaka  K. Tateiwa
Affiliation:a Process Development Department, Process Technology Development Div., Renesas Technology Corp., 4-1, Mizuhara, Itami-shi, Hyogo 664-0005, Japan
b ULSI Process Technology Development Center, Semiconductor Company, Matsushita Electric Industrial Co., Ltd., 19, Nishikujo-kasuga-cho, Minami-ku, Kyoto 601-8413, Japan
Abstract:The oxidation on nickel silicide (NiSix) during plasma etching and oxygen ashing is investigated for stable contact resistance on NiSix. NiSix exposed by various processes is observed by X-ray photoelectron spectroscopy. The oxidation on NiSix is promoted by the fluorine that remains during etching and the oxide thickness on n+ NiSix is greater than that on p+ NiSix. The remaining fluorine after etching can be decreased by in-situ nitrogen plasma treatment during the post-etching process. Therefore, the oxidation progress with exposure to air and the difference in oxidation on NiSix between n+ and p+ can be suppressed.
Keywords:Etching   X-ray photoelectron spectroscopy   Nickel   Oxidation
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