| 2,4,6-三硝基-2,4,6-三氮杂环己酮的合成研究进展 |
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| 引用本文： | 马丛明,刘祖亮,姚其正.2,4,6-三硝基-2,4,6-三氮杂环己酮的合成研究进展[J].含能材料,2013,21(1):126-130. |
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| 作者姓名： | 马丛明 刘祖亮 姚其正 |
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| 作者单位： | 1. 南京理工大学化工学院,江苏南京,210094
2. 南京理工大学化工学院,江苏南京210094;中国药科大学药学院,江苏南京210009 |
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| 摘 要： | 汇集、分析、评述了合成2,4,6-三硝基-2,4,6-三氮杂环己酮(Keto-RDX)的方法、途径、特点及原料和硝化体系。附22篇参考文献。认为:以脲和乌洛托品为原料合成Keto-RDX的直接法具有反应步骤少、成本低、产率高的优点和难分离提纯产物的缺点,而通过1,3,5-三嗪类中间体合成Keto-RDX的多步法具有反应步骤多,成本高的缺点和易分离提纯产物的优点。
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| 关 键 词： | 有机化学 RDX酮 含能材料 合成 |
| 收稿时间： | 2012/3/27 0:00:00 |
| 修稿时间： | 2012/4/20 0:00:00 |
Progresss in Synthesis of 2,4,6-Trinitro-2,4,6-triazacyclohexanone |
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| MA Cong-ming,LIU Zu-liang and YAO Qi-zheng.Progresss in Synthesis of 2,4,6-Trinitro-2,4,6-triazacyclohexanone[J].Chinese Journal of Energetic Materials,2013,21(1):126-130. |
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| Authors: | MA Cong-ming LIU Zu-liang and YAO Qi-zheng |
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| Affiliation: | 1,2(1.School of Chemical Engineering,Nanjing University of Science & Technology,Nanjing 210094,China;2.School of Pharmacy,China Pharmaceutical University,Nanjing 210009,China) |
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| Abstract: | The strategies, methods, paths, characters, starting materials and nitrating systems of synthesizing 2, 4, 6-trinitro-2, 4, 6-triazacyclohexanone(Keto-RDX) were summarized, analysized and reviewed with 22 references. Considering that direct method using urotropine and urea as starting materials has the advantages of less steps, lower cost and higher yield and the disadvantages of difficult separation and purification from a mixtures of Keto-RDX and RDX, while the multistep method of synthesizing Keto-RDX via 1, 3, 5-triazine intermediates has the disadvantages of more reaction steps and higher cost and the advantages of easier separation and purification. |
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| Keywords: | organic chemistry Keto-RDX energetic material synthesis |
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