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Performance properties of microcrystalline cellulose as a reinforcing agent in wood plastic composites
Authors:Alireza Ashori  Amir Nourbakhsh
Affiliation:1. Department of Chemical Industries, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran;2. Department of Wood and Paper Science, Research Institute of Forests and Rangelands (RIFR), Tehran, Iran;1. Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;2. Department of Chemical Engineering, College of Engineering, King Saud University, Riyadh, Saudi Arabia;3. Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;1. Fibrous Materials Research Group, School of Engineering, University of Minho, Campus de Azurém, 4800-058, Guimarães, Portugal;2. Department of Civil Engineering, School of Engineering, University of Minho, Campus de Azurém, 4800-058, Guimarães, Portugal;3. Federal University of Technology – Paraná, Apucarana, 80230-901, Brazil;1. Bioengineering and Environmental Sciences Lab, Department of Energy and Environmental Engineering, CSIR-Indian Institute of Chemical Technology (CSIR-IICT), Hyderabad, 500 007, India;2. Academy of Scientific and Innovative Research (AcSIR), CSIR-Indian Institute of Chemical Technology (CSIR-IICT) Campus, Hyderabad, India
Abstract:Polypropylene (PP)/microcrystalline cellulose (MCC)/wood flour composites were prepared containing polypropylene-graft-maleic anhydride (PP-g-MA) as compatibilizer. The mechanical, morphological and thermal properties were investigated. The weight ratio of the cellulosic materials to polymer matrix was 40:60 (w:w). The obtained results showed that tensile, flexural and impact strengths of the composites were significantly enhanced with addition of MCC, as compared with pure PP and composites without MCC. The effect of MCC on impact was minimal compared to the effects of PP-g-MA content. Scanning electron microscopy has shown that the composite, with compatibilizer, promotes better fiber–matrix interaction. In all cases, the degradation temperatures shifted to higher values after addition of PP-g-MA. The maximum improvement on the thermal stability of the composites was achieved when 5% PP-g-MA was used. However, the increase in MCC content substantially reduced the thermal stability. This work showed that MCC along with wood flour could be effectively used as reinforcing agent in thermoplastic matrix.
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