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The effect of adding carbon nanotubes to glass/epoxy composites in the fibre sizing and/or the matrix
Authors:Ashish Warrier  Ajay Godara  Olivier Rochez  Luca Mezzo  Frederic Luizi  Larissa Gorbatikh  Stepan V Lomov  Aart Willem VanVuure  Ignaas Verpoest
Affiliation:1. Departement of Metallurgy and Materials Engineering Katholieke Universiteit, Leuven Kasteelpark Arenberg 44, B-3001 Leuven, Belgium;2. Department of Research and Development, Nanocyl S.A., Rue de I´ Essor 4, B-5060 Sambreville, Belgium;1. School of Statistics and Applied Mathematics, Anhui University of Finance and Economics, Bengbu 233030, China;2. Young Researchers and Elites Club, Science and Research Branch, Islamic Azad University, Tehran, Iran;3. Department of Mechanical Engineering, College of Engineering, Kyung Hee University, Yongin 446-701, Republic of Korea;1. Department of Mechanical and Manufacturing Engineering, University Putra Malaysia, 43400 Serdang, Selangor, Malaysia;2. Materials and Processing Laboratory, Institute of Advanced Technology, University Putra Malaysia, 43400 Serdang, Selangor, Malaysia;3. Department of Chemical and Environmental Engineering, University Putra Malaysia, 43400 Serdang, Selangor, Malaysia;4. Department of Aerospace Engineering, University Putra Malaysia, 43400 Serdang, Selangor, Malaysia;1. Laboratoire de Mécanique des Sols, Structures et Matériaux, École Centrale Paris, CNRS UMR8579, Grande Voie des Vignes, 92290 Châtenay-Malabry, France;2. Department of Polymer Science and Engineering, University of Science & Technology Beijing, Beijing 100083, People’s Republic of China;3. Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong Special Administrative Region;1. Department of Materials Science and Engineering, Technion-Israel Institute of Technology, Haifa 32000, Israel;2. Materials Engineering & Technology Development, Engineering & Development Group, Israel Aerospace Industries Ltd., Ben-Gurion International Airport, 70100, Israel;3. Department of Mechanical Engineering, Technion-Israel Institute of Technology, Haifa 32000, Israel;1. Department of Mechanical Engineering, State University of New York at Binghamton, Binghamton, NY 13902, USA;2. College of Engineering, University of Georgia, Athens, GA 30602, USA;3. NASA Langley Research Center, Hampton, VA 23681, USA;4. Department of Mechanical and Aerospace Engineering, University of Virginia, Charlottesville, VA 22904, USA
Abstract:Carbon nanotubes (CNTs) were integrated in glass fibres epoxy composites by either including CNTs in the fibre sizing formulation, in the matrix, or both. The effects of such controlled placement of CNTs on the thermophysical properties (glass transition temperature and coefficient of thermal expansion) and the Mode I interlaminar fracture toughness of the composites were studied. The present method of CNT-sizing of the glass fibres produces an increase of almost +10% in the glass transition temperature and a significant reduction of ?31% in the coefficient of thermal expansion of the composites. Additionally, the presence of CNTs in the sizing resulted in an increased resistance of crack initiation fracture toughness by +10%, but a lowered crack propagation toughness of ?53%. Similar trends were observed for both instances when CNTs were introduced only in the matrix and in combination of both matrix and sizing.
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