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高包容模拟放射性核素Sr固化技术研究
引用本文:梁磐仪,陈泉水,马辉,郁兴国,刘晓东.高包容模拟放射性核素Sr固化技术研究[J].陶瓷学报,2011,32(2):197-201.
作者姓名:梁磐仪  陈泉水  马辉  郁兴国  刘晓东
作者单位:1. 东华理工大学材料科学与工程系,江西抚州344000;东华理工大学核资源与环境教育部重点实验室,江西南昌330013
2. 东华理工大学材料科学与工程系,江西抚州,344000
摘    要:以氧化铁、钛粉、氧化钙、二氧化钛为原料,利用溶胶-凝胶反应制备了人造钙钛矿岩石。以人造岩石为基底,利用固相反应固化模拟放射性核素Sr。借助X射线衍射(XRD)、扫描电子显微镜(SEM)等方法分析固化体形貌与结构。结果分析表明:当Fe2O3∶Ti∶CaO∶TiO2=2∶3∶4∶1(物质的量之比),掺入SrO含量为10%时,可以获得较好的钙钛矿物相。

关 键 词:溶胶凝胶  人造钙钛矿  模拟固化  性能分析

High Containment Technology for Immobilizing Simulated Radioactive Element Sr
LIANG Panyi,CHEN Quanshui,MA Hui,YU Xingguo,LIU Xiaodong.High Containment Technology for Immobilizing Simulated Radioactive Element Sr[J].Journal of Ceramics,2011,32(2):197-201.
Authors:LIANG Panyi  CHEN Quanshui  MA Hui  YU Xingguo  LIU Xiaodong
Affiliation:LIANG Panyi 1,2 CHEN Quanshui 1,2 MA Hui 1 YU Xingguo 1 LIU Xiaodong 1(1.Department of Material Science and Engineering,East China Institute of Technology,Fuzhou Jiangxi 344000,China,2.Key Laboratory of Nuclear Resources and Environment of Ministry of Education,Nanchang Jiangxi 330013,China)
Abstract:Perovskite synroc was synthesized by the sol-gel method,using Fe2O3,Ti,CaO and TiO2 as main raw materials,and simulated radioactive element Sr was immobilized in pervoskite synroc matrix through solid-state reaction.The as-formed sample was then analyzed by X-ray diffraction and scanning electron microscopy.The results indicate that the best result can be obtained when the mol ratio of Fe2O3∶Ti∶CaO∶TiO2=2∶3:4:1 and the doping amount of SrO is 10%.
Keywords:sol-gel  perovskite synroc  simulated immobilization  performance analysis  
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