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Highly active MgO-supported TiCl4 catalyst for the ethylene polymerization
Authors:Norio Kashiwa  Toshiyuki Tsutsui
Affiliation:(1) Research Center, Mitsui Petrochemical Industries, Ltd., Waki-cho, Kuga-gun, 740 Yamaguchi-ken, Japan
Abstract:Summary The MgO-supported TiCl4 catalysts prepared by heating MgO with TiCl4 showed a high activity for the ethylene polymerization in combination with Et3Al or i-Bu3Al. In these highly active catalysts, it has been shown that MgCl2 is formed in the MgO-TiCl4 reaction and is considered to contribute to the enhancement of the activity of the catalysts.
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