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Cu~(2+)、吡啶、环烷酸三元配合物的组成研究
引用本文:陈英,陈东,刘宝生.Cu~(2+)、吡啶、环烷酸三元配合物的组成研究[J].广东化工,1999(4).
作者姓名:陈英  陈东  刘宝生
作者单位:广东石油化工高等专科学校化工系,茂名石油化工公司南海高级润滑油公司,广东石油化工高等专科学校化工系 茂名,25000,茂名,25000
摘    要:通过摩尔比法(饱和法)对Cu~(2+)、吡啶(Py)、环烷酸(R)三元配合物的组成进行了研究,并通过环烷酸铜、Cu~(2+)、Py、R三元配合物和吡啶红外光谱图对Cu~(2+)、Py、R 三元配合物的结构进行了分析,认为此三元配合物的组成为Cu~(2+):吡啶:环烷酸=1:4:2,且为缔合型三元配合物,其结构简式为Cu(Py)_4]R_2。

关 键 词:三元配合物  Cu~(2+)  吡啶  环烷酸

The research about the composition of three-complex of Cu~(2+) and pyridine and naphthenic acid
Chen Ying.The research about the composition of three-complex of Cu~(2+) and pyridine and naphthenic acid[J].Guangdong Chemical Industry,1999(4).
Authors:Chen Ying
Abstract:The composition of three-complex of Cu and pyridine(Py) and naphthenic acid(R) has been researched by mol ratio method(saturation method)in the paper, and the structure of the three-complex has been anasised by the infra-red spectrograms of naphtrenic acid nantokite and the three-complex and pyridine, concluding the results that composition of the three-complex is Cu2+:pyridine:naphthenic acid= 1:4:2 and the model of the three-complex is associated model (the sample structure is Cu(Py)4]R2.
Keywords:thrre-complex  Cu~(2+)  pyridine  naphenic acid  
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