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The effect of temperature on the growth of carbon nanotubes on copper foil using a nickel thin film as catalyst
Authors:G Atthipalli  R EpurPN Kumta  BL AllenY Tang  A StarJL Gray
Affiliation:
  • a Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, PA 15261, USA
  • b Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
  • c Department of Bioengineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
  • d Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15261, USA
  • Abstract:Growth of carbon nanotubes (CNTs) on bulk copper foil substrates has been achieved by sputtering a nickel thin film on Cu substrates followed by thermal chemical vapor deposition. The characteristics of the nanotubes are strongly dependent on the Ni film thickness and reaction temperature. Specifically, a correlation between the thin film nickel catalyst thickness and the CNT diameter was found. Two hydrocarbon sources investigated were methane and acetylene to determine the best conditions for growth of CNTs on copper. These results demonstrate the effectiveness of this simple method of directly integrating CNTs with highly conductive substrates for use in applications where a conductive CNT network is desirable.
    Keywords:Thin films  Sputtering  Carbon nanotubes  Thermal chemical vapor deposition  X-ray diffraction  Scanning electron microscopy
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