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800H合金的高温抗氧化性能
引用本文:程晓农,王荣荣,李冬升,戴起勋,黄燕,刘瑜,陶亚平.800H合金的高温抗氧化性能[J].材料热处理学报,2012,33(6):95-99.
作者姓名:程晓农  王荣荣  李冬升  戴起勋  黄燕  刘瑜  陶亚平
作者单位:1. 江苏大学材料科学与工程学院,江苏镇江,212013
2. 江苏银环精密钢管股份有限公司,江苏宜兴,214203
基金项目:江苏省科技成果转化项目,省级重点实验室开放课题
摘    要:利用X射线衍射仪(XRD)、扫描电镜(SEM)和能谱仪(EDS)等,对800H合金高温氧化膜的增厚动力学、形貌及氧化物组成进行了分析。结果表明,700和800℃下形成的氧化膜相近,由(Cr,Fe)2O3和Mn-Cr氧化物组成;900℃时的氧化膜急剧增厚,里层依然是Cr2O3,中间层则是Cr-Fe-Mn氧化物,外层为富Ti的氧化物。通过热力学和动力学计算,提出了800H合金氧化膜形成的模型,发现TiN的存在改变了氧化膜的结构。

关 键 词:800H合金  高温氧化  氧化膜  热力学计算

Oxidation resistance of alloy 800H at elevated temperature
CHENG Xiao-nong,WANG Rong-rong,LI Dong-sheng,DAI Qi-xun,HUANG Yan,LIU Yu,TAO Ya-ping.Oxidation resistance of alloy 800H at elevated temperature[J].Transactions of Materials and Heat Treatment,2012,33(6):95-99.
Authors:CHENG Xiao-nong  WANG Rong-rong  LI Dong-sheng  DAI Qi-xun  HUANG Yan  LIU Yu  TAO Ya-ping
Affiliation:1.School of Materials Science and Technology,Jiangsu University,Zhenjiang 212013,China; 2.Jiangsu Yinhuan Precision Steel Tube Co Ltd,Yixing 214203,China)
Abstract:Oxidation kinetics,morphology and constitution of oxides formed on alloy 800 H at high temperature were analyzed by means of X-ray diffraction,scanning electron microscopy and energy dispersive spectroscopy.The results show that the scales formed at 700 ℃ are similar to that formed at 800 ℃,mainly composed of(Cr,Fe)2O3 and Mn-Cr oxides.The scales formed at 900 ℃ are much thicker with three layers: an inner layer of Cr2O3,an interlayer of Cr-Fe-Mn oxides and an outer layer of Ti-riched oxides.The oxidation of 800H alloy is simulated by thermodynamics and kinetics calculation,and TiN particles are considered to change the scales structure.
Keywords:alloy 800H  high temperature oxidation  oxide scales  thermodynamic calculation
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