Near‐Infrared Small Molecule Acceptor Enabled High‐Performance Nonfullerene Polymer Solar Cells with Over 13% Efficiency |
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Authors: | Wei Gao Tao Liu Ruijie Ming Zhenghui Luo Kailong Wu Lin Zhang Jingming Xin Dongjun Xie Guangye Zhang Wei Ma He Yan Chuluo Yang |
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Affiliation: | 1. Department of Chemistry and Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Wuhan University, Wuhan, P. R. China;2. Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and Engineering, Shenzhen University, Shenzhen, P. R. China;3. Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration & Reconstruction, Hong Kong University of Science and Technology, Kowloon, Hong Kong;4. State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, P. R. China |
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Abstract: | One of the most promising approaches to achieve high‐performance polymer solar cells (PSCs) is to develop nonfullerene small molecule acceptors (SMAs) with an absorption extending to the near‐infrared (NIR) region. In this work, two novel SMAs, namely, BTTIC and BTOIC, are designed and synthesized, with optical bandgaps (Egopt) of 1.47 and 1.39 eV, respectively. Desipte the narrow Egopt, the PBDB‐T:BTTIC‐ and PBDB‐T:BTOIC‐based PSCs can maintain high VOCs of over 0.90 and 0.86 V, respectively, with low energy losses (Eloss) < 0.6 eV. Meanwhile, due to the favorable morphology of the PBDB‐T:BTTIC blend, balanced carrier mobilities are achieved. The high external quantum efficiencies enable a high power conversion efficiency (PCE) up to 13.18% for the PBDB‐T:BTTIC‐based PSCs. In comparison, BTOIC shows an excessive crystallization propensity owing to its oxyalkyl side groups, which eventually leads to a relatively low PCE for the PBDB‐T:BTOIC‐based PSCs. Overall, this work provides insights into the design of novel NIR‐absorbing SMAs for nonfullerene PSCs. |
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Keywords: | high performance solar cells near‐infrared acceptors nonfullerene solar cells polymer solar cells small molecule acceptors |
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