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A study on designing a paired electrolysis for electro-induced Michael addition using tetrafluoroborate-based ionic liquid as electrolysis medium and pre-catalyst in a divided cell
Authors:Laura Palombi
Affiliation:Dept. of Chemistry and Biology, University of Salerno, via Ponte Don Melillo, 84081 Fisciano (Sa), Italy
Abstract:Simultaneous double electro-induced synthesis of Michael adducts in both the compartments of a divided cell has been achieved by galvanostatic electrolysis in 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid, exploiting the direct electro-generation of the enolate in the cathodic side and the electro-generation of the Lewis acid BF3 in the anodic side of the cell.
Keywords:Paired electrolysis  Michael addition  Ionic liquids  Green electrosynthesis
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