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Effects of H2/NH3 flow-rate ratio on the luminescent, structural, and electrical properties of GaN epitaxial layers grown by MOCVD
Authors:Chien-Cheng Yang  Pao-Ling Koh  Meng-Chyi Wu  Chih-hao Lee  Gou-Chung Chi
Affiliation:(1) Department of Electrical Engineering, National Tsing Hua University, 300 Hsinchu, Taiwan, ROC;(2) Opto-Electronics and Systems Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan, ROC;(3) Department of Physics, National Central University, 320 Chung-Li, Taiwan, ROC;(4) Department of Engineering and System Science, National Tsing Hua University, 300 Hsinchu, Taiwan, ROC
Abstract:GaN epitaxial layers were grown on sapphire substrates in a separate-flow reactor by metalorganic chemical vapor deposition. The flow-rate ratio of H2 on the upper stream to NH3 on the bottom stream is varied from 0.5 to 2. The growth condition and characterization of the GaN epitaxial layers are investigated in detail. The H2 flow rate of the upper stream strongly affects the reactant gas flow pattern near the substrate surface and thus influences the quality of epitaxial layers. At the optimum H2/NH3 flow ratio of 1.0, we can obtain a good quality of GaN epitaxial layers which exhibit a strong near band-edge emis-sion in the 20 K photoluminescence (PL), a full width at half maximum of 66 meV for the 300 K PL, an electron mobility of 266 cm2/V-s and concentration of 1 × 1018 cm−3 at 300 K.
Keywords:GaN  high band-gap energy  photoluminescence (PL)  x-ray diffraction (DC-XRD)
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