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Preparation of Pectin-Based Biosorbents for Cadmium and Lead Ions Removal
Authors:Agata Jakóbik-Kolon  Andrzej K Milewski  Krzysztof Mitko  Andrea Lis
Affiliation:1. Department of Inorganic, Analytical Chemistry, and Electrochemistry, Faculty of Chemistry, Silesian University of Technology, Gliwice, Polandagata.jakobik@polsl.pl;3. Department of Inorganic, Analytical Chemistry, and Electrochemistry, Faculty of Chemistry, Silesian University of Technology, Gliwice, Poland
Abstract:The optimal formation conditions of pectin-based, as well as new hybrid pectin-guar gum, biosorbents were found. The lead affinity for obtained biosorbents was very strong even in solution of pH = 1, in opposite to cadmium, which was adsorbed from solutions of pH ≥ 2. The sorption capacities in the studied conditions were about 0.6 and 0.8 mmol/g for cadmium and lead, respectively. The cadmium removal could be fast and it is almost quantitatively desorbed using 0.25 M HNO3, while desorption of lead required 1 M HNO3 to achieve a removal efficiency of ca. 75% from pectin-based beads. The possibility of biosorbents’ reuse was also proved. Addition of guar gum to pectin biosorbent did not change its sorption properties significantly.
Keywords:biosorption  cadmium  guar gum  lead  pectin
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