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2.25Cr-1Mo合金钢回火脆化过时效现象的研究
引用本文:周昌玉,孙宇,张国栋.2.25Cr-1Mo合金钢回火脆化过时效现象的研究[J].特殊钢,2006,27(2):6-8.
作者姓名:周昌玉  孙宇  张国栋
作者单位:南京工业大学机械与动力工程学院,南京 210009
摘    要:研究了2.25Cr-1Mo合金钢在回火温度下时效处理时,发生回火脆化和回火脆化的过时效反偏聚现象。应用非平衡偏聚的动力学理论,确定了成分(%)为0.15C、2.32Cr、0.95Mo、0.009P的2.25Cr-1Mo合金钢在650℃140 h回火时钢中磷的非平衡晶界偏聚规律。试验得出,2.25Cr-1Mo合金钢650℃磷非平衡偏聚的临界时间tc为20 h,晶界磷的原子浓度,由初始状态的0.016%提高至最大值2.79%。根据试验数据进行的动力学计算,得出的计算曲线与试验结果吻合,验证了非平衡晶界偏聚空位-复合体模型的扩散机制。

关 键 词:2.25Cr-1Mo合金钢  回火脆化  非平衡偏聚  过时效  
收稿时间:10 10 2005 12:00AM
修稿时间:2005年10月10

A Study on Temper Embrittlement Overaging Phenomenon of Alloy Steel 2.25Cr-1Mo
Zhou Changyu,Sun Yu,Zhang Guodong.A Study on Temper Embrittlement Overaging Phenomenon of Alloy Steel 2.25Cr-1Mo[J].Special Steel,2006,27(2):6-8.
Authors:Zhou Changyu  Sun Yu  Zhang Guodong
Affiliation:College of Mechanical and Power Engineering, Nanjing University of Technology, Nanjing 210009
Abstract:The tempering embrittlement and its overaging phenomenon (counter^segregation) of alloy steel 2.25Cr-1Mo at tempering temperature have been studied. The non-equilibrium segregation law of phosphorus in alloy steel 2.25Cr-1Mo (0.15C, 2.32Cr, 0.95Mo, 0.009P) tempering at 650 °C for 140 h was obtained with using the kinetics theory of non-equilibrium segregation r The test results showed that critical time tc of phosphorus non-equilibrium segregation in alloy steel 2.25Cr-1Mo at 650 ℃ was 20 h, at this time the atomic concentration of phosphorus at grain boundary increased to maximum value 2.79% from 0.016% at original status. According to kinetic calculation of test data, the obtained calculated curve conformed with the test results which verified the diflusion mechanism of non-equilibrium grain segregation for vacancy-complex model.
Keywords:Alloy Steel 2  25Cr-1Mo  Temper Embrittlcmcnt  Non-Equillbrium Segregation  Overaging
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