| Pd/C催化剂催化分解甲酸反应动力学研究 |
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| 引用本文： | 方向红,郑争志,张寅秋,崔鹏. Pd/C催化剂催化分解甲酸反应动力学研究[J]. 安徽化工, 2009, 35(2): 23-24 |
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| 作者姓名： | 方向红 郑争志 张寅秋 崔鹏 |
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| 作者单位： | 合肥工业大学化学工程学院,安徽,合肥,230009;合肥工业大学化学工程学院,安徽,合肥,230009;合肥工业大学化学工程学院,安徽,合肥,230009;合肥工业大学化学工程学院,安徽,合肥,230009 |
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| 摘 要： | 采用湿空气氧化法研究了常压下Pd/C催化剂催化分解甲酸的反应动力学。建立了甲酸催化分解反应速率经验方程,Pd/C催化分解甲酸在323～363K范围内表观活化能为22.1kJ·mol-1。
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| 关 键 词： | 甲酸 Pd/C催化剂 催化分解 动力学 |
Kinetic Study of the Catalytic Decomposition of HCOOH on Pd/C Catalyst |
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| FANG Xiang-hong,ZHENG Zheng-zhi,ZHANG Yin-qiu,CUI Peng. Kinetic Study of the Catalytic Decomposition of HCOOH on Pd/C Catalyst[J]. Anhui Chemical Industry, 2009, 35(2): 23-24 |
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| Authors: | FANG Xiang-hong ZHENG Zheng-zhi ZHANG Yin-qiu CUI Peng |
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| Affiliation: | School of Chemical Engineering;Hefei University of Technology;Hefei 230009;China |
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| Abstract: | The kinetics of the catalytic decomposition of HCOOH on Pd/C catalyst by wet air oxidative method was investigated alter the influence of internal and external diffusion was eliminated. Based on the study of the reaction time and the reaction temperature, an experience rate equation was established. In the temperature range of 323 - 363 K, the activation energy E, is 22.1 kJ·mol^-1 |
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| Keywords: | Formic acid Pd/C catalyst catalytic decomposition kinetics |
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