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催化—离子选择电极法测定微量银的研究
引用本文:李利军 吴文启. 催化—离子选择电极法测定微量银的研究[J]. 广西工学院学报, 1995, 6(2): 59-61
作者姓名:李利军 吴文启
作者单位:广西工学院科研处,柳州商检局
摘    要:利用银作催化剂,催化分解氧化亚铁氰化钾,并用离子选择电极测定分解产物氰离子,其电位值(Ep)与一定浓度范围的银(I)成较好的线性关系,检出限为4.2ng/ml。该法用于水样中微量银的测定,结果满意。

关 键 词:银 电极法 微量分析 水分析

Determination of Silver by Catalytic-ion Selective Electrode Method
Li Lijun. Determination of Silver by Catalytic-ion Selective Electrode Method[J]. Journal of Guangxi University of Technology, 1995, 6(2): 59-61
Authors:Li Lijun
Abstract:Ag(I) has catalytic effect on disintegration and oxidation of K4Fe(CN)6. The ion Selective electrode has been applied to determining cyanic ion, which is one of the disintegration product. The potential (Ep) is good linear to concentration of silver. Therefore, the trace amounts of silver can be determined, the detection limit is 4. 2ng/ml. The method can be used for water analysis with satisfaction.
Keywords:Silver  Catalytic-ion selective electrode method  K_4Fe(CN)_6  
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