| D-氨基葡萄糖与硝酸铕、铽配合物的合成及光谱分析 |
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| 引用本文： | 任群翔,翟玉春,孙莹莹,封丽.D-氨基葡萄糖与硝酸铕、铽配合物的合成及光谱分析[J].化学世界,2010,51(10). |
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| 作者姓名： | 任群翔 翟玉春 孙莹莹 封丽 |
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| 作者单位： | 1. 沈阳医学院化学教研室,辽宁,沈阳,110034
2. 东北大学材料与冶金学院,辽宁,沈阳,110004 |
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| 摘 要： | 用D-氨基葡萄糖盐酸盐分别与硝酸铕和硝酸铽反应,制备了氨基葡萄糖-铕、氨基葡萄糖-铽两种配合物,并研究了配合物的红外光谱、紫外光谱和X射线光电子能谱(XPS)。配合物紫外的λmax发生了明显紫移,在远IR区Glu-Eu配合物中出现的新的吸收峰206 cm-1和254 cm-1可分别归属于νEu-O和νEu-N,在Glu-Tb配合物中出现的新的吸收峰203 cm-1和252 cm-1可分别归属于νTb-O和νTb-N,XPS表明氨基葡萄糖-Ln中氨基葡萄糖的N和O原子上的电子云密度减少,孤对电子转移,稀土离子得到电子。
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| 关 键 词： | 氨基葡萄糖 稀土配合物 合成 光谱分析 |
Synthesis and Spectral Analysis of Coordination Compounds of Glucosamine with Eu(NO3)3 and Tb(NO3)3 |
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| REN Qun-xiang,ZHAI Yu-chun,SUN Ying-ying,FENG Li.Synthesis and Spectral Analysis of Coordination Compounds of Glucosamine with Eu(NO3)3 and Tb(NO3)3[J].Chemical World,2010,51(10). |
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| Authors: | REN Qun-xiang ZHAI Yu-chun SUN Ying-ying FENG Li |
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| Abstract: | The Glu-Eu and Glu-Tb coordination compounds were synthesized from D-glucosamine hydrochloride with Eu(NO_3)_3 and Tb(NO_3)_3,respectively.IR,UV and X-ray photoelectron spectroscopy of the compexes were studied.In UV spectra,the λ_(max) of the complexes showed obvious violet shift when compared with that of the glucosamine.In far infrared spectra of the complexes,two new bands 206 cm～(-1) and 254 cm～(-1) appeared for Glu-Eu compound which were attributed to ν_(Eu-O) and ν_(Eu-N),while another two new bands 203 cm～(-1) and 252 cm～(-1) appeared in Glu-Tb compound attributed to ν_(Tb-O) and ν_(Tb-N).XPS results indicated that the electron pair of the N atom and O atom of glucosamine shifted to the rare earth ion. |
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| Keywords: | D-glucosamine rare earth coordination compound synthesis spectral analysis |
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