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A novel biomimetic approach to the design of high-performance ceramic–metal composites
Authors:Maximilien E Launey  Etienne Munch  Daan Hein Alsem  Eduardo Saiz  Antoni P Tomsia  Robert O Ritchie
Affiliation:1.Materials Sciences Division, University of California, Berkeley, CA 94720, USA;2.National Center for Electron Microscopy, University of California, Berkeley, CA 94720, USA;3.Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA
Abstract:The prospect of extending natural biological design to develop new synthetic ceramic–metal composite materials is examined. Using ice-templating of ceramic suspensions and subsequent metal infiltration, we demonstrate that the concept of ordered hierarchical design can be applied to create fine-scale laminated ceramic–metal (bulk) composites that are inexpensive, lightweight and display exceptional damage-tolerance properties. Specifically, Al2O3/Al–Si laminates with ceramic contents up to approximately 40 vol% and with lamellae thicknesses down to 10 µm were processed and characterized. These structures achieve an excellent fracture toughness of 40 MPa√m at a tensile strength of approximately 300 MPa. Salient toughening mechanisms are described together with further toughening strategies.
Keywords:ceramics  metals  composites  toughness  strength  freeze-casting
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