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A novel Route to Synthesize <Emphasis Type="Italic">p</Emphasis>-Terphenyl from Benzene by the Catalysis of h-BN Nanoparticles
Authors:Hongyun Li  Yongzhong Wu  Xiangang Xu
Affiliation:(1) High School Affiliated to Shandong University, Shandong University, 27 Shanda Nanlu, Jinan, 250100, People’s Republic of China;(2) State Key Laboratory of Crystal Materials, Shandong University, 27 Shanda Nanlu, Jinan, 250100, People’s Republic of China
Abstract:We have investigated the catalytic effect of boron nitride (h-BN) nanoparticles. The experiments prove that p-terphenyl can be synthesized from benzene at 400 °C in the presence of h-BN nanoparticles, thereby implying that the observed catalytic property of the h-BN nanoparticles may expand the application field of inorganic nanocrystals. The paper also discusses the mechanism of the structural rearrangement and oligomerization from benzene to p-terphenyl.
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