Bifunctional MOF‐Derived Carbon Photonic Crystal Architectures for Advanced Zn–Air and Li–S Batteries: Highly Exposed Graphitic Nitrogen Matters |
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Authors: | Meijia Yang Xuanhe Hu Zhengsong Fang Lu Sun Zhongke Yuan Shuangyin Wang Wei Hong Xudong Chen Dingshan Yu |
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Affiliation: | 1. Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Key Laboratory of High Performance Polymer‐Based Composites of Guangdong Province, School of Chemistry, Sun Yat‐Sen University, Guangzhou, P. R. China;2. State Key Laboratory of Chem/Bio‐Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, P. R. China |
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Abstract: | Nitrogen‐rich porous carbons (NPCs) are the leading cathode materials for next‐generation Zn–air and Li–S batteries. However, most existing NPC suffers from insufficient exposure and harnessing of nitrogen‐dopants (NDs), constraining the electrochemical performance. Herein, by combining silica templating with in situ texturing of metal–organic frameworks, a new bifunctional 3D nitrogen‐rich carbon photonic crystal architecture of simultaneously record‐high total pore volume (13.42 cm3 g?1), ultralarge surface area (2546 m2 g?1), and permeable hierarchical macro‐meso‐microporosity is designed, enabling sufficient exposure and accessibility of NDs. Thus, when used as cathode catalysts, the Zn–air battery delivers a fantastic capacity of 770 mAh gZn?1 at an unprecedentedly high rate of 120 mA cm?2, with an ultrahigh power density of 197 mW cm?2. When hosting 78 wt% sulfur, the Li–S battery affords a high‐rate capacity of 967 mAh g?1 at 2 C, with superb stability over 1000 cycles at 0.5 C (0.054% decay rate per cycle), comparable to the best literature value. The results prove the dominant role of highly exposed graphitic‐N in boosting both cathode performances. |
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Keywords: | graphitic nitrogen Li– S batteries metal– organic frameworks photonic crystals Zn– air batteries |
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