Recent Progress in Ionic Iridium(III) Complexes for Organic Electronic Devices

Ionic iridium(III) complexes are emerging with great promise for organic electronic devices, owing to their unique features such as ease of molecular design and synthesis, excellent photophysical properties, superior redox stability, and highly efficient emissions of virtually all colors. Here, recent progress on new material design, regarding photo‐ and electroluminescence is highlighted, including several interesting topics such as: i) color‐tuning strategies of cationic iridium(III) complexes, ii) widespread utilization in phosphorescent light‐emitting devices fabricated by not only solution processes but also vacuum evaporation deposition, and iii) potential applications in data record, storage, and sercurity. Results on anionic iridium(III) complexes and “soft salts” are also discussed, indicating a new related subject. Finally, a brief outlook is suggested, pointing out that ionic iridium(III) complexes should play a more significant role in future organic electronic materials technology.