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活性炭孔结构及润湿性对混合型超级电容器电化学性能的影响
引用本文:胡耀强,刘希邈,张丽明,詹亮,凌立成. 活性炭孔结构及润湿性对混合型超级电容器电化学性能的影响[J]. 炭素, 2007, 0(1): 9-11
作者姓名:胡耀强  刘希邈  张丽明  詹亮  凌立成
作者单位:华东理工大学,联合化学反应工程国家重点实验室,上海,200237
摘    要:以Ni(OH)2和活性炭为正负极组成复合电化学电容器。用氮吸附和接触角测定润湿性以恒流充、放电等表征方法,研究孔径、比表面积、浸润性对混合电容器电化学性能的影响。结果表明:高润湿性的活性炭有利于电容器容量的提高;具有较多中孔含量的活性炭有利于电容器大电流充放电性能的提高。

关 键 词:活性炭  浸润性  比表面积  超级电容器
文章编号:1001-8948(2007)01-0009-03
修稿时间:2006-08-09

EFFECTS OF PORE STRUCTURE AND WET CHARACTERISTIC ON THE ELECTROCHEMICAL PERFORMANCE OF THE HYBRID SUPERCAPACITORS
Hu Yao-qiang,Liu Xi-miao,Zhang Li-ming,Zhan liang,Ling Li-cheng. EFFECTS OF PORE STRUCTURE AND WET CHARACTERISTIC ON THE ELECTROCHEMICAL PERFORMANCE OF THE HYBRID SUPERCAPACITORS[J]. Carbon(China), 2007, 0(1): 9-11
Authors:Hu Yao-qiang  Liu Xi-miao  Zhang Li-ming  Zhan liang  Ling Li-cheng
Affiliation:East China University of Science and Technology(ECUST
Abstract:Hybrid supercapacitors were fabricated using Ni (OH)_2 positive negative and electrodes of activat- ed carbon.The effects of the pore size distribution,BET specific surface and wet characteristic on the ca- pacitance and high power charge discharge performance of the supercapacitors were discussed by means of nitrogen gas adsorption,wetting angle measurement and constant current charge discharge techniques.Re- sults show that activated carbon with high wet characteristic and high existence of mesopore structure can give large capacitance and good high power charge and discharge performance.
Keywords:activated carbon   wet characteristic    BET    supercapacitors
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