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溶胶-凝胶法制备低折射率和低介电常数介孔二氧化硅薄膜
引用本文:沈军,欧阳玲,林雪晶,谢志勇,罗爱云.溶胶-凝胶法制备低折射率和低介电常数介孔二氧化硅薄膜[J].稀有金属材料与工程,2008,37(Z2):76-79.
作者姓名:沈军  欧阳玲  林雪晶  谢志勇  罗爱云
作者单位:同济大学,波耳固体物理研究所,上海,200092
基金项目:National Natural Science Foundation of China(Grant No.20133040,69978017,50572073),Chinese National Foundation of High Technology(2002AA842052),Shanghai Key Subject Program,Shanghai Phosphor Program(05QMH1413),and Trans-Century Training Program Foundation for the Talents by Ministry of Education of People's Republic of China
摘    要:采用溶胶-凝胶技术,蒸发诱导自组装法(EISA)工艺制备了二氧化硅透明有序介孔薄膜.以十六烷基三甲基溴化铵(CTAB)作为模板剂,正硅酸乙酯(TEOS)为硅源前驱体,基片采用双面抛光的硅片,利用提拉法制备薄膜.经过表面修饰剂六甲基二硅胺烷(HMDS)修饰后,薄膜具有疏水性能,而且薄膜的二氧化硅骨架结构更稳定.由椭偏仪测得热处理后的薄膜的折射率低至1.18,而薄膜的介电常数为2.14.

关 键 词:介孔薄膜  溶胶-凝胶  低折射率  低介电常数
文章编号:1002-185X(2008)S2-330-04
修稿时间:2007年11月22

Preparation of Low-k and Low-n Mesoporous Silica Films via Sol-Gel Process
Shen Jun,Ouyang Ling,Lin Xuejing,Xie Zhiyong,Luo Aiyun.Preparation of Low-k and Low-n Mesoporous Silica Films via Sol-Gel Process[J].Rare Metal Materials and Engineering,2008,37(Z2):76-79.
Authors:Shen Jun  Ouyang Ling  Lin Xuejing  Xie Zhiyong  Luo Aiyun
Abstract:Mesopomus silica films were successfully prepared through sol-gel process with evaporation-induced self-assembly.Tetraethoxysilane(TEOS)was used as silica precursor and Cetyltrimethylammonium bromide(CTAB)as the templating agent.The films were deposited on the silicon wafer or glass substrate using a dip-coating method.The refractive index(k)of the mesoporous films was 1.18,while the dielectric constant(n)was 2.14.
Keywords:mesoporous films  sol-gel  low dielectric constant  low refractive index
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