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增塑型超韧尼龙11的力学性能和增塑机理
引用本文:李齐方,金日光,冯威,陈松. 增塑型超韧尼龙11的力学性能和增塑机理[J]. 材料研究学报, 2000, 14(3): 265-270
作者姓名:李齐方  金日光  冯威  陈松
作者单位:北京化工大学高分子材料国家重点学科
基金项目:国家自然科学基金!59443011,国家九五攻关项目!95-532-01-06
摘    要:增塑后尼龙11的冲击强度及断裂伸长率大幅提高,但断裂强度并未大幅降低。尼龙11的增塑机理是,增塑剂破坏了尼龙11的分子间氢键作用。研究表明,增塑型超韧尼龙11的断裂面具有独特的形态,这是一种首次发现的新型断裂现象。本文首次将上述现象归结为“多重裂延”机理。

关 键 词:尼龙11 增塑 超韧 力学性能 多层裂延 断裂机理
文章编号:1005-3093(2000)03-0265-06
修稿时间:1999-03-09

MECHANICAL PROPERTIES AND TOUGHENING MECHANISM OF PLASTICIZING TYPE SUPER TOUGHENING NYLON 11
LI Qifang,JIN Riguang,FENG Wei,CHEN Song. MECHANICAL PROPERTIES AND TOUGHENING MECHANISM OF PLASTICIZING TYPE SUPER TOUGHENING NYLON 11[J]. Chinese Journal of Materials Research, 2000, 14(3): 265-270
Authors:LI Qifang  JIN Riguang  FENG Wei  CHEN Song
Abstract:The mechanical properties of plasticizing nylon 11 system were overall investigated.For plasticizing nylon 11 system, the plasticizing efficiency was different for different plasticizers. After plasticized, the impact strength (>900J/m) and elongation of nylon 11 increased remarkably, and tensile strength did not decrease too much. The mechanism of plasticized nyklon 11 was that plasticizer destroyed the hydrogen bond of nylon 11. The fracture research of plasticized nylon 11 showed that fracture morphology was very special for supertoughening nylon 11, this new fracture was first found in toughening materials. Based on the experimental fracture truth, the new mechanism" multi-layer crack extension" was first put forward.
Keywords:nylon 11   toughening   plasticizer   mechanical property   toughening mechanism
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