Optimization of chalcogenide glass in the As–Se–S system for automotive applications |
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| Authors: | Erwan Guillevic Xianghua Zhang Thierry Pain Laurent Calvez Jean-Luc Adam Jacques Lucas Maryline Guilloux-Viry Sophie Ollivier Gregory Gadret |
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| Affiliation: | aLaboratory of Glasses and Ceramics, UMR CNRS 6226 “Sciences Chimiques de Rennes”, Université de Rennes I, campus de Beaulieu, 35042 Rennes cedex, France;bChimie du solide et matériaux, Sciences chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, France;cInstitut Carnot de Bourgogne, UMR-CNRS 5209, Department OMR, 9 Allée Alain Savary BP 47870, 21078 DIJON Cedex, France |
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| Abstract: | Infrared transmitting glasses in the As–Se–S system have been optimized by taking in account specifications for automotive application. The As2Se3 glass has been chosen as the starting composition and sulfur is introduced in order to improve some optical and mechanical properties. As expected, the Sulfur introduction decreases the refractive index as well as its change as function of temperature. The relationship between the refractive index and the glass composition has been established. The thermal coefficient of refractive index for sulfur containing glasses can be lower than 4 × 10−5 K−1, which is considerably lower than that of germanium, the most used infrared transmitting materials. Influence of sulfur on other properties has also been studied. |
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| Keywords: | Chalcogenide glasses dn/dT Infrared transmission |
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