| 氯铝酸盐离子液体催化转移烷基化反应研究 |
| |
| 引用本文： | 吴伟,肖林飞,徐敏,武光,闫鹏飞,马方伟,基赫佳宁O.V.. 氯铝酸盐离子液体催化转移烷基化反应研究[J]. 化学与粘合, 2010, 32(6): 5-8,21 |
| |
| 作者姓名： | 吴伟 肖林飞 徐敏 武光 闫鹏飞 马方伟 基赫佳宁O.V. |
| |
| 作者单位： | 黑龙江省普通高校高效转化的化工过程与技术重点实验室,中俄联合催化实验室,黑龙江大学,化学化工与材料学院,哈尔滨,150080;黑龙江省普通高校高效转化的化工过程与技术重点实验室,中俄联合催化实验室,黑龙江大学,化学化工与材料学院,哈尔滨,150080;俄罗斯科学院鲍列斯科夫催化研究院,俄罗斯,新西伯利亚,630090 |
| |
| 基金项目： | 黑龙江省自然科学基金,黑龙江省教育厅科学技术研究,哈尔滨市科技攻关计划 |
| |
| 摘 要： | 制备了阳离子分别为盐酸三乙胺、1-甲基-3-丁基咪唑和N-丁基吡啶的三种氯铝酸盐离子液体,并通过27AlNMR和吡啶及乙腈吸附的红外光谱等手段对其结构和酸性进行了表征,比较了上述三种离子液体催化2-甲基萘与1,2,4,5-四甲苯转移烷基化的反应性能。结果表明,阳离子结构不同的三种离子液体具有不同的催化性能,Et3NHCl-2AlCl3离子液体具有最高的催化反应活性和较高的2,6-二甲基萘选择性,在20℃下反应8h,2-甲基萘的转化率和2,6-二甲基萘选择性分别为36.8%和62.3%。
|
| 关 键 词： | 氯铝酸盐离子液体 转移烷基化 2 6-二甲基萘 选择性 |
Tram Alkylation Catalyzed by Chloroaluminate Ionic Liquids |
| |
| WU Wei,XIAO Lin-fei,XUN Min,WU Guang,YAN Peng-fei,MA Fang-wei,KICHTIANIN O.V. Tram Alkylation Catalyzed by Chloroaluminate Ionic Liquids[J]. Chemistry and Adhesion, 2010, 32(6): 5-8,21 |
| |
| Authors: | WU Wei XIAO Lin-fei XUN Min WU Guang YAN Peng-fei MA Fang-wei KICHTIANIN O.V |
| |
| Affiliation: | WU Wei , XIAO Lin-fei, XUN Min, WU Guang,YAN Peng-fei,MA Fang-wen and KICHTIANIN O.V (1. Key Laboratory of Chemical Engineering Process＆Technology for High-effwiency Conversion, College of Heilongjiang Province, Sino-Russan Joint Laboratory for Catalysis ,College of Chemistry and Material Sciences, Heilongiang University, Harbin 150080, China; 2.Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Scienees, Novosibirsk 630090, Russia) |
| |
| Abstract: | A series of chloroaluminate ionic liquids, whose cations were triethylaminia hydrochloride, 1-methyl-3-hutylimidazolium and N- butylpyridiniu, respectively, was prepared and its catalytic performance was examined in the transalkylation of 2-methylnaphthalene with 1,2,4,5- tetramethylbenzene. The 27Al NMR measurement was carried out to determine the existing form of aluminum complex in ionic liquids and the acidity of ionic liquids was characterized by the pyridine and acetonitrile adsorbed FT-IR. The results indicted that the catalytic performance of the ionic liquids with various cations was different and the highest catalytic activity and the higher selectivity for 2,6-dimethylnaphthalene were obtained when the ionic liquid Et3HCl-2AlCl3 was used as a catalyst. When the transalkylation was carried out at 20℃ for 8h, the 36.8% conversion of 2-methyl- naphthalene and the 62.3% selectivity of 2,6-dimethylnaphthalene were obtained. |
| |
| Keywords: | Chloroaluminate ionic liquids transalkylation 2,6-dimethylnaphthalene selectivity |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
