| 低温低压甘油氢解制备1,2-丙二醇新工艺的研究 |
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| 引用本文： | 刘芃,朱小学,郑敏,叶秋云,李楠锌.低温低压甘油氢解制备1,2-丙二醇新工艺的研究[J].天然气化工,2012,37(1):17-20. |
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| 作者姓名： | 刘芃 朱小学 郑敏 叶秋云 李楠锌 |
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| 作者单位： | 西南化工研究设计院,成都,610225 |
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| 摘 要： | 在固定床两步反应器系统中研究甘油氢解制1,2-丙二醇,考察了催化剂(Cu/SiO2、Cu/ZnO/Al2O3、Cu/MnO/Al2O3)和反应温度、系统压力、氢气空速和甘油浓度等工艺参数的影响。结果开发出一种使用Cu/SiO2催化剂的甘油氢解制丙二醇的低温低压固定床两步法新工艺,该工艺有较高的甘油转化率和1,2-丙二醇选择性。
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| 关 键 词： | 甘油 氢解 1 2-丙二醇 铜基催化剂 低温低压工艺 |
A novel low-temperature and low-pressure process for hydrogenolysis of glycerol to 1,2-propanediol |
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| LIU Peng
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ZHU Xiao-xue
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ZHEN Min
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YE Qiu-yun
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LI Nan-xin.A novel low-temperature and low-pressure process for hydrogenolysis of glycerol to 1,2-propanediol[J].Natural Gas Chemical Industry,2012,37(1):17-20. |
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| Authors: | LIU Peng ZHU Xiao-xue ZHEN Min YE Qiu-yun LI Nan-xin |
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| Affiliation: | (The Southwest Research and Design Institute of Chemical Industry,Chengdu 610225,China) |
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| Abstract: | The hydrogenolysis of glycerol to 1,2-propanediol was studied in a fixed-bed two-step reactor system.The effects of the catalysts,Cu/SiO2,Cu/ZnO/Al2O3 and Cu/MnO/Al2O3,and the process parameters,reaction temperature,pressure,hydrogen space velocity and glycerol concentration,were investigated.This research resulted in the development of a novel low-temperature and low-pressure fixed-bed two-step process for hydrogenolysis of glycerol to 1,2-propanediol,which used Cu/SiO2 as catalyst and had high glycerol conversion and 1,2-propanediol selectivity. |
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| Keywords: | glycerol hydrogenolysis 1 2-propanediol Cu-based catalyst low-temperature and low-pressure process |
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