| 导电聚合物/纳米银复合薄膜的制备及特性研究 |
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| 引用本文： | 杨亚杰,闻俊峰,蒋亚东,张鲁宁,徐建华. 导电聚合物/纳米银复合薄膜的制备及特性研究[J]. 稀有金属材料与工程, 2015, 44(11): 2902-2906 |
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| 作者姓名： | 杨亚杰 闻俊峰 蒋亚东 张鲁宁 徐建华 |
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| 作者单位： | 电子科技大学 电子薄膜与集成器件国家重点实验室，四川 成都 610054 |
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| 基金项目： | 国家自然科学基金（61101029） |
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| 摘 要： | 采用化学气相聚合法制备了聚3,4-乙烯二氧噻吩(PEDOT))/纳米银复合薄膜,研究了复合纳米薄膜的导电及电化学性能。研究结果表明,PEDOT/纳米银复合薄膜的电导率为54.8 S/cm,高于纯PEDOT薄膜的电导率(17.3 S/cm),复合纳米薄膜的比容量为174.5 F/g,明显高于纯PEDOT薄膜的比容量。循环测试1000次后,复合膜的比容量保持率为81.6%,具有良好的电化学稳定性。这种化学气相聚合制备的聚合物复合纳米薄膜在超级电容器及导电材料领域有着良好的应用前景。
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| 关 键 词： | 化学气相聚合；纳米银；超级电容器；比容量；电导率 |
| 收稿时间： | 2015-04-25 |
Preparation and Characterization of Conducting Polymer/Nano Silver Composites |
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| Yang Yajie,Wen Junfeng,Jiang Yadong,Zhang Luning and Xu Jianhua. Preparation and Characterization of Conducting Polymer/Nano Silver Composites[J]. Rare Metal Materials and Engineering, 2015, 44(11): 2902-2906 |
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| Authors: | Yang Yajie Wen Junfeng Jiang Yadong Zhang Luning Xu Jianhua |
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| Affiliation: | State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China |
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| Abstract: | A chemical vapor-phase polymerization (VPP) method was employed to prepare poly-3,4-ethylenedioxythiophene/nano silver nanocomposites. The electrical and electrochemical performance of the nanocomposites was investigated. The conductive results show that PEDOT/nano silver exhibits conductivity ca. 54.8 S/cm, which is higher than pure PEDOT films (17.3 S/cm). This PEDOT/nano silver composites exhibits higher specific capacitance (ca. 174.5 F/g) than pure PEDOT due to the high specific surface area of nano silver. The cycle performance reveals that the nanocomposites keep 81.6% initial capacitance after 1000 cycles, indicating excellent cycling stability. This VPP PEDOT nanocomposites show promising application in supercapacitor and conducting materials. |
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| Keywords: | chemical vapor-phase polymerization graphene oxide reduced graphene oxide supercapacitor conductivity |
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