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Interfacial reactions of liquid Sn and Sn-3.5Ag solders with Ag thick films
Authors:T L Su  L C Tsao  S Y Chang  T H Chuang
Affiliation:(1) Department of Materials Science and Engineering, National Taiwan University, 106 Taipei, Taiwan, China
Abstract:The interfacial reactions of liquid Sn and Sn-3.5Ag solders with Ag thick films are investigated in the temperature range from 250–325 °C, and the morphology of intermetallic compounds formed after such soldering reactions is observed. In kinetics analysis of the growths of intermetallic compounds, it was found that both Sn/Ag and Sn-3.5Ag/Ag reactions were interfacial-controlled, and the growth rates for both cases were similar. The rate of Ag dissolution into liquid solder attendant on the formation of interfacial intermetallic compounds after Sn/Ag reaction was about four times higher than that after Sn-3.5Ag/Ag reaction, as evidenced by experimental results.
Keywords:Ag dissolution  Ag3Sn intermetallic compound  Ag thick film  Sn/Ag  Sn-3  5Ag/Ag  soldering reactions
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