| 草铵膦制备合成方法简述 |
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| 引用本文： | 宋宏涛,楚士晋. 草铵膦制备合成方法简述[J]. 现代农药, 2006, 5(3): 1-3,30 |
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| 作者姓名： | 宋宏涛 楚士晋 |
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| 作者单位： | 西南科技大学材料学院,四川绵阳,621010;中国工程物理研究院核物理与化学研究所,四川绵阳,621900 |
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| 基金项目： | 西南科技大学创新基金资助项目(CX050504) |
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| 摘 要： | 根据相关文献报道,比较分析了以往草铵膦的制备合成方法,并结合其合成特点,提出了合成草铵膦的新型方法——“阿布佐夫–迈克尔法”。该方法基于阿布佐夫重排反应和迈克尔加成反应,所用原料简单,路线设计合理,较为经济实用。
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| 关 键 词： | 草铵膦 合成 阿布佐夫重排 迈克尔加成 |
| 文章编号： | 1671-5284（2006）03-0001-03 |
| 收稿时间： | 2005-10-21 |
| 修稿时间： | 2005-10-212006-03-23 |
Summary of Synthetic Methods of Glufosinate-ammonium |
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| SONG Hong-tao,CHU Shi-jin. Summary of Synthetic Methods of Glufosinate-ammonium[J]. Modern Agrochemicals, 2006, 5(3): 1-3,30 |
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| Authors: | SONG Hong-tao CHU Shi-jin |
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| Affiliation: | 1. College of Material, Southwest University of Science and Technology, Sichuan Mianyang 621010, China; 2. Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Sichuan M ianyang 621900, China |
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| Abstract: | According to the correlative references, the former synthesis methods of glufosinate-ammonium were introduced and analyzed. Based on the synthesis character of glufosinate-ammonium as well as Arbuzov and Michael reaction,a novel and reasonable scheme was put forward as the more economical and practical one with simple reagents. |
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| Keywords: | glufosinate-ammonium synthesis Arbuzov rearrangement Michael addition |
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