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The structure of carbon filaments and associated catalytic particles formed during pyrolysis of natural gas in steel tubes
Authors:J.R. Bradley   Y.-L. Chen  H.W. Sturner
Affiliation:1. College of Science, Xi''an University of Science and Technology, Xi''an, 710054, China;2. College of Physics and Information Technology, Shaanxi Normal University, Xi''an, 710119, China;1. School of Nuclear Technology and Chemistry & Biology, Hubei University of Science and Technology, Xianning 437100, China;2. Department of Energy Materials and Technology, General Research Institute for Nonferrous Metals, Beijing, China;3. Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong SAR, China;4. School of Materials Science and Engineering, Nanchang University, Nanchang, Jiangxi 330031, China;1. Department of Physics, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran;2. Center for Research on Laser and Plasma, Shahid Chamran University of Ahvaz, Ahvaz, Iran
Abstract:New information is presented on the structure and growth of carbon filaments formed in association with catalytic metal or metal carbide particles during pyrolysis of natural gas. The structures of the filaments and of the particles have been examined by transmission electron microscopy. The filaments are hollow, ~0.1 μm or less in diameter, and vermicular as opposed to straight. The graphite basal planes are frequently not parallel to the axis of the filament. Individual catalyst particles have been identified as (Fe,Cr)23C6 when pyrolysis occurs in a stainless steel tube and as γ-iron in a plain carbon steel tube.
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