| Abstract: | The deoxidation equilibrium for Al in Ni-Fe alloys was studied in the equilibrium experiments between CaO-Al2O3 slags and Fe-30, 50 and 70 % Ni alloys at 1873 K. By using the values for the first and second order interaction parameters between oxygen and nickel in liquid iron and those between oxygen and iron in liquid nickel, the effect of Ni on the activity coefficient of Al in liquid iron and that of Fe on the activity coefficient of Al in liquid nickel were determined in the whole composition range of Ni-Fe alloys. The oxygen contents in Ni-Fe alloys calculated by the iterative method based on pure iron were in good agreement with those based on pure nickel in the range of % Al] < 0.03. From this fact, it was found that the Wagner's approximation relating to the multi-component solution was applicable to the deoxidation equilibrium in the whole composition range of Ni-Fe alloys in the restricted concentration of a deoxidizer. |
