Concomitant Crystallization of Copper(II) Sachharinato Complexes with 2-methylpyrazine as a Monomer and an One-dimensional Polymer: Syntheses,Crystal Structures,Spectroscopic and Thermal Properties |
| |
| Authors: | Veysel T. Yilmaz Evrim Senel Canan Kazak |
| |
| Affiliation: | (1) Department of Chemistry, Faculty of Arts and Sciences, Uludag University, 16059 Gorukle, Bursa, Turkey;(2) Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Kurupelit, Samsun, Turkey;(3) Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Kurupelit, Samsun, Turkey |
| |
| Abstract: | The reaction of [Cu(sac)2(H2O)4] · 2H2O with 2-methylpyrazine (mpyz) leads two complexes, concomitant crystallization of a mononuclear complex [Cu(sac)2(mpyz)(H2O)2] (1) and a polymeric complex [Cu(sac)2(μ-mpyz)]n (2). Both complexes have been characterized by elemental analyses, magnetic measurements, FT-IR and ESR, TG-DTA and single-crystal X-ray diffraction analyses. Single-crystal X-ray analyses show that complex 1 consists of discrete molecules in which the copper(II) ions exhibits a square-pyramidal coordination geometry. The individual molecules of 1 are connected into a hydrogen-bonded chain structure, which is further assembled to form a three-dimensional network by π–π stacking interactions. Complex 2 is an 1D coordination polymer in which copper(II) centers are bridged by the mpyz ligand. The chains are further assembled to form two-dimensional frameworks by π–π and C–H···π stacking interactions. |
| |
| Keywords: | Saccharinate 2-methylyrazine Copper(II) complex Coordination polymer One-dimensional chain Two-dimensional framework |
| 本文献已被 SpringerLink 等数据库收录！ |
|
