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Chemical absorption and desorption of carbon dioxide from hot carbonate solutions
Authors:David W Savage  Gianni Astarita  Shriram Joshi
Affiliation:Corporate Applied Research, Exxon Research and Engineering Co., Linden, NJ 07036, U.S.A.;Istituto di Principi di Ingegneria Chimica, Universita di Napoli, Italy;Chemical Engineering Department, University of Delaware, Newark, DE 19711, U.S.A.
Abstract:Absorption and desorption rate data for the system CO2-hot carbonate solutions are presented. The data are interpreted on the basis of a film-theory model developed following the procedure recently presented by Astarita and Savage 1]. The agreement is very satisfactory. Values of the kinetic constant of the rate-determining step, previously known only up to a temperature of 40°C, have been obtained up to 110°C.
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