| 四(4-磺酸苯基)卟啉的微波合成 |
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| 引用本文： | 赵胜芳,陈年友,张丽华,李早英. 四(4-磺酸苯基)卟啉的微波合成[J]. 化学试剂, 2005, 27(2): 119-120 |
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| 作者姓名： | 赵胜芳 陈年友 张丽华 李早英 |
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| 作者单位： | 黄冈师范学院,化学系,湖北,黄冈,438000;武汉大学,化学与分子科学学院,湖北,武汉,430072 |
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| 基金项目： | 湖北省教育厅重点科研项目 (1999A0 83 ,2 0 0 2A0 40 0 2 )基金资助。 |
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| 摘 要： | 用微波辐射加热合成了四(4-磺酸苯基)卟啉。考察了微波作用的时间、微波辐射功率、反应试剂的组成与用量等因素对产物产率的影响。
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| 关 键 词： | 四苯基卟啉(TPP) 四(4-磺酸苯基)卟啉(TPPS4) 微波合成 磺化 |
| 文章编号： | 0258-3283(2005)02-0119-02 |
The microwave synthesis of tetra (p-sulphonic phenyl) porphyrin |
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| ZHAO Sheng-fang,CHEN Nian-you,ZHANG Li-hua,Li Zao-ying. The microwave synthesis of tetra (p-sulphonic phenyl) porphyrin[J]. Chemical Reagents, 2005, 27(2): 119-120 |
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| Authors: | ZHAO Sheng-fang CHEN Nian-you ZHANG Li-hua Li Zao-ying |
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| Affiliation: | ZHAO Sheng-fang *1,CHEN Nian-you1,ZHANG Li-hua1,LI Zao-ying2 |
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| Abstract: | This paper discusses the synthesis of tetra(p-sulphonic phenyl) porphyrin by microwave irradiation and the influence of the time and the power of microware radiation,the proportion and quantity of reagents upon the synthetic yield.The experiment showed that compared with traditional heating methods,the use of cheap concentrated sulfuric acid shortened the reaction time by three quarters and increased the yield by 5 percent;besides,the side reaction became less and the crude product was easier to be separated. |
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| Keywords: | tetraphenylporphyrin tetra(p-sulphonic phenyl)porphyrin microwave-synthesis sulphonation |
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