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Thermodynamic Calculation on the Vaporization of Fission-Produced Noble Metal System in Vacuum and Oxidative Atmosphere at High Temperatures
Abstract:The vaporization behavior of fission-produced noble metal system (Mo-Ru-Pd, Mo-Ru-Rh and Mo-Tc-Pd) in vacuum and oxidative atmosphere at high temperatures was investigated by the thermodynamic calculation on the basis of the regular solution model and the available experimental data. The palladium and rhodium in the allyoys, and molybdenum and ruthenium in the alloys vaporize preferentially at high temperature in vacuum and in ari, respectively. At low temperature below 385K in air, ruthenium and technetium in the alloys vaporize predominantly by oxidation.
Keywords:thermodynamic calculation  thermodynamic properties  vaporization  vapors  fission-produced noble metal system  vacuum  oxidative atmosphere  high temperature  ruthenium  technetium  palladium  rhodium  alloys  oxidation
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