a Central Research Institute of Electric Power Industry, Iwato-kita 2-11-1, Komae-shi, Tokyo 201, Japan
b Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki-ken 319-11, Japan
Abstract:
Interdiffusion experiments were carried out at 923 K with the diffusion couples consisting of U–23 at.% Zr/Fe and U–23 at.% Zr–1 at.% Ce/Fe. The reaction layer adjacent to the Fe was a single Zr-depleted UFe2 phase. The phases in the reaction layers were estimated consistently with the calculated U–Zr–Fe ternary isotherm. The diffusion path obtained in this study was similar to that reported for the U–Pu–Zr/HT9-steel couple at 923 K, when those paths were expressed on the (U+Pu)–Zr–(Fe+Cr) composition triangle. The reaction layers grew in proportion to the square root of the annealing time. The addition of approximately 1 at.% of Ce to the U–23 at.% Zr alloy has little effect on the reaction between U–23 at.% Zr and Fe.