| 碘催化苯甲醚的苯甲酰化反应 |
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| 引用本文： | 梁红,吴艳华,吴爽,陈平. 碘催化苯甲醚的苯甲酰化反应[J]. 石油化工高等学校学报, 2011, 24(6): 75-78. DOI: 10.3696/j.issn.1006-396X.2011.06.019 |
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| 作者姓名： | 梁红 吴艳华 吴爽 陈平 |
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| 作者单位： | 辽宁石油化工大学化学与材料科学学院 |
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| 基金项目： | 国家自然科学青年基金资助项目(21003069) |
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| 摘 要： | 在碘催化作用下，以苯甲醚和苯甲酰氯为原料，通过Friedel-Crafts酰基化反应合成对甲氧基二苯甲酮。考察了原料物质的量比、催化剂用量以及反应温度和时间等因素对产品收率的影响。确定的适宜工艺条件为: 苯甲醚0.1 mol，苯甲醚与苯甲酰氯的物质的量比为1.0∶1.5，催化剂质量为1. 5 g，反应温度140 ℃，反应时间为4. 0 h ，产物收率达59.0%。
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| 关 键 词： | 碘 苯甲醚 苯甲酰氯 对甲氧基二苯甲酮 |
| 收稿时间： | 2011-12-06 |
Benzoylation Reaction of Anisole Using Iodine as Catalyst |
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| LIANG Hong,WU Yan-hua,WU Shuang,CHEN Ping. Benzoylation Reaction of Anisole Using Iodine as Catalyst[J]. Journal of Petrochemical Universities, 2011, 24(6): 75-78. DOI: 10.3696/j.issn.1006-396X.2011.06.019 |
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| Authors: | LIANG Hong WU Yan-hua WU Shuang CHEN Ping |
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| Affiliation: | (School of Chemistry and Materials Science,Liaoning Shihua University,Fushun Liaoning 113001,P.R.China) |
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| Abstract: | 4-Methoxybenzophenone was synthesized from Fridel-crafts acylation of anisole and benzoyl chloride using iodine as catalyst.The effects of reactant ratio,amount of catalyst used,reaction temperature and time were investigated.The suitable reaction conditions were optimized as: anisole was 0.1 mol,anisole / benzoyl chloride mole ratio was 1.0∶1.5,catalyst usage was 1.5 g,reaction temperature was 140 ℃,reaction time was 4 h.The highest yield of 61.68 % is obtained. |
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| Keywords: | Iodine anisole Benzoyl chloride 4-Methoxybenzophenone |
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