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石墨/聚氨酯弹性体复合材料的制备及性能研究
引用本文:张志毅,薛艺,刘亚青,贾林才. 石墨/聚氨酯弹性体复合材料的制备及性能研究[J]. 聚氨酯工业, 2013, 0(3): 14-17
作者姓名:张志毅  薛艺  刘亚青  贾林才
作者单位:山西省高分子复合材料工程技术研究中心;中北大学材料科学与工程学院;山西省化工研究所
摘    要:采用原位插层聚合,通过预聚体法合成石墨/聚氨酯弹性体(PUE)复合材料,经X-射线衍射(XRD)和扫描电子显微镜(SEM)测试表明,石墨在聚氨酯弹性体中的分散性和相容性较好;当石墨质量分数小于15%时,随着石墨含量增加,PUE复合材料的拉伸强度、300%定伸强度、撕裂强度和扯断伸长率不断升高;石墨质量分数进一步增加到30%时,其相关力学性能又开始下降,硬度稍有增加。综合分析,PUE复合材料表现出较好的力学性能。

关 键 词:聚氨酯弹性体  石墨  插层聚合

Synthesis and Characterization of Graphite/Polyurethane Elastomer Composites
Zhang Zhiyi,Xue Yi,Liu Yaqing,Jia Lincai. Synthesis and Characterization of Graphite/Polyurethane Elastomer Composites[J]. Polyurethane Industry, 2013, 0(3): 14-17
Authors:Zhang Zhiyi  Xue Yi  Liu Yaqing  Jia Lincai
Affiliation:1.Research Center for Engineering Technology of Polymeric Composites,Taiyuan 030051,China)(2.Department of Materials Science and Engineering,North University of China,Taiyuan 030051,China)(3.Shanxi Provincial Institute of Chemical Industry,Taiyuan 030021,China)
Abstract:The graphite/polyurethane elastomer composite was synthesized through pre-polymerized method by in situ intercalative polymerization technology. The X-ray diffraction and scanning electron microscopy (SEM) showed that the graphite was well dispersed in polyurethane matrix and had better compatibility. The tensile strength, 300% stretching strength, tearing strength and elongation at break were increased w.hen the graphite mass fraction less than 15%. The related mechanical properties were decreased and the hardness had a little increased when the graphite mass fraction increased to 30%. Comprehensive evaluation, the graphite/polyurethane elastomer composite had better mechanical properties.
Keywords:polyurethane elastomer  graphite  intercalative polymerization
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