水溶性含氮杯芳烃的合成

以对叔丁基杯4]芳烃为原料，在无水三氯化铝存在下，与苯酚发生脱烷基化反应合成了杯E4]芳烃。再以杯4]芳烃与对氨基苯磺酸为原料，通过偶合反应合成了5，11，17，23-四（对磺基苯基）偶氮]-杯E4]芳烃，再利用锡-盐酸还原得到5，1i，17，23-四氨基-杯4]芳烃盐酸盐。合成的化合物通过热分析、红外光谱和紫外光谱等对合成的各化合物分析。利用该方法合成杯4]芳烃铵的盐酸盐收率高，成本大大降低。

Synthesis of Water-Soluble Nitrogen-Containing Calixarene

Calix -4] arene was synthesized by dealkylation reaction using p-tert-butylcalix 4] arene and phenol as raw material in the presence of anhydrous A1C13. Then 5,11,17,23-four sulfo phenyl） azo calix 4] arene was synthesized by coupling reaction using calix 4] arene and p-amino benzene sulfonic acid as raw materials. In the presence of tin-hydrochloric acid, 5,11,17,23-four sulfo phenyl）-azo calix 42 arene was reduced to 5,11,17,23 four amino-calix 4] arene hydrochloride. The synthesized compounds were characterized by thermal analysis, infrared spectrum analysis and UV spectra of the synthesized compounds. By using the method of synthesis of calix 4] arene ammonium hydrochloride yield is high, cost is greatly reduced.