固化条件对热塑增韧环氧树脂的固化动力学和相分离的影响EI

采用砂型和金属型两种不同铸造方法对铸态、固溶态和时效态ZL210A合金性能及断口形貌的影响进行研究.结果表明:对ZL210A铸造合金而言,金属型铸造方法优于砂型铸造方法,其常规力学性能σb,σ0.2和δ5均高于砂型铸造,从断口形貌上看,试样断口形貌均呈现典型的穿晶断裂,且韧窝较深.其中,金属型固溶态试样的断口韧窝最为明显,呈现出较好的韧性.

Effect of Casting Methods on Mechanical Properties and Fracture Surfaces of ZL210A Casting Aluminum Alloy

Thermoplastic toughened epoxy resins are widely used as matrices in modern prepreg systems.Different curing conditions play a great role in affecting the cure kinetics and phase behaviour of thermoplastic modified epoxies which further result in different mechanical properties of polymer matrix composites.Since the morphology of the cured thermoplastic/epoxy blends is directly related to the mechanical properties,it is essential to control processing conditions for obtaining desirable morphology.A polyethersulphone (PES) modified multifunctional epoxies,triglycidylaminophenol (TGAP) and tetraglycidyldiaminodiphenylmethane (TGDDM),was used for investigation.The cure kinetics and cured morphology of polymer blends heated at different heating rates and cured at different temperature were studied.It is shown that higher cure temperature and higher heating rate display similar effects in the epoxy conversion and the domain size of phase separated structure.