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燃烧法制备二氧化钛催化剂的条件对其可见光催化性能的影响
引用本文:程友萍,孙红旗,金万勤,徐南平.燃烧法制备二氧化钛催化剂的条件对其可见光催化性能的影响[J].中国化学工程学报,2007,15(2):178-183.
作者姓名:程友萍  孙红旗  金万勤  徐南平
作者单位:Membrane Science and Technology Research Center, Nanjing University of Technology, Nanjing 210009, China
基金项目:Supported by the Key Laboratory of Material-0riented Chemical Engineering of Jiangsu Province and Ministry of Education.
摘    要:Titania catalysts were synthesized by a solution combustion method (SCM). Photodegradation of 4-chlorophenol (4-CP) using the synthesized catalysts was studied under both visible light (λ≥420nm) and sunlight irradiation. The effect of preparation conditions on photocatalytic activities of the synthesized catalysts was investigated. The optimal photocatalytic activity of the catalyst (denoted as A1 ) was obtained under the following synthesis conditions: ignition temperature of 350~C, fuel ratio ( φ) of 1 and calcination time of lh. The degradation and mineralization ratio of 4-CP were 78.2% and 53.7% respectively under visible light irradiation for 3h using catalyst A1. And the catalyst A1 also showed high photocatalytic activity under sunlight irradiation.

关 键 词:二氧化钛  溶液燃烧法  合成  光催化活性  制备条件  可见光
收稿时间:31 March 2006
修稿时间:2006-03-312006-09-15

Effect of preparation conditions on visible photocatalytic activity of titania synthesized  by solution combustion method
CHENGYouping,SUNHongqi,JINWanqin,XUNanping.Effect of preparation conditions on visible photocatalytic activity of titania synthesized  by solution combustion method[J].Chinese Journal of Chemical Engineering,2007,15(2):178-183.
Authors:CHENGYouping  SUNHongqi  JINWanqin  XUNanping
Affiliation:Membrane Science and Technology Research Center,Nanjing University of Technology,Nanjing 210009,China;Membrane Science and Technology Research Center,Nanjing University of Technology,Nanjing 210009,China;Membrane Science and Technology Research Center,Nanjing University of Technology,Nanjing 210009,China;Membrane Science and Technology Research Center,Nanjing University of Technology,Nanjing 210009,China
Abstract:Titania catalysts were synthesized by a solution combustion method (SCM).Photodegradation of 4-chlorophenol (4-CP) using the synthesized catalysts was studied under both visible light (λ≥420nm) and sunlight irradiation.The effect of preparation conditions on photocatalytic activities of the synthesized catalysts was investigated.The optimal photocatalytic activity of the catalyst (denoted as A1) was obtained under the following synthesis conditions:ignition temperature of 350℃,fuel ratio (φ) of 1 and calcination time of 1h.The degradation and mineralization ratio of 4-CP were 78.2% and 53.7% respectively under visible light irradiation for 3h using catalyst A1. And the catalyst A1 also showed high photocatalytic activity under sunlight irradiation.
Keywords:TiO2  solution combustion method  photodegradation  visible light
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