| 合成方法对Ru-Zn/ZrO2苯部分加氢催化剂的影响 |
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| 引用本文： | 董森,刘树俊,郭学华.合成方法对Ru-Zn/ZrO2苯部分加氢催化剂的影响[J].工业催化,2021,29(4):64-67. |
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| 作者姓名： | 董森 刘树俊 郭学华 |
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| 作者单位： | 开滦煤化工研发中心,河北 唐山063611;河北省煤基材料与化学品技术创新中心,河北 唐山063018 |
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| 摘 要： | 分别采用水热-共沉淀法和机械混合法制备Ru-Zn/ZrO_(2)催化剂,并用于苯部分加氢制环己烯反应体系。通过XRD、SEM、TEM等对催化剂的组成、结构和形貌进行表征,对比不同方法合成的催化剂对苯部分加氢反应的影响。结果表明,水热-共沉淀法制备的Ru-Zn/ZrO_(2)催化剂上的Ru分散度高,晶粒尺寸小,催化剂表面苯加氢位点多,在较低的Ru用量情况下,即可获得较高的苯转化率和环己烯收率。
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| 关 键 词： | 催化剂工程 水热-共沉淀法 Ru-Zn催化剂 苯部分加氢 环己烯 |
Effect of prearation on Ru-Zn/ZrO2 catalyst for partial hydrogenation of benzene |
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| Dong Sen,Liu Shujun,Guo Xuehua.Effect of prearation on Ru-Zn/ZrO2 catalyst for partial hydrogenation of benzene[J].Industrial Catalysis,2021,29(4):64-67. |
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| Authors: | Dong Sen Liu Shujun Guo Xuehua |
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| Affiliation: | 1. Kailuan Coal Chemical R&D Center,Tangshan 063611,Hebei,China;2. Hebei Provincial Technology Innovation Centre of Coal-based Materials and Chemicals,Tangshan 063018,Hebei,China |
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| Abstract: | Ru-Zn/ZrO2 catalysts for partial hydrogenation of benzene to cyclohexene were prepared by hydrothermal co-precipitation and mechanical mixing method respectively.The composition,structure and morphology of samples were characterized by XRD,SEM and TEM.The effects of synthesis methods on the hydrogenation of benzene were explored.The results show that Ru-Zn/ZrO2 catalyst prepared by hydrothermal precipitation method was favor to obtain metallic Ru with high dispersion,small grain size and more benzene hydrogenation sites on the catalyst surface.Higher benzene conversion and cyclohexene yield can be obtained at lower Ru dosage. |
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| Keywords: | catalyst engineering hydrothermal-precipitation method Ru-Zn catalyst partial hydrogenation of benzene cyclohexene |
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