| 硅钨杂多酸催化合成戊二酸二正戊酯 |
| |
| 引用本文： | 邹明旭.硅钨杂多酸催化合成戊二酸二正戊酯[J].精细石油化工进展,2001,2(1):4-6. |
| |
| 作者姓名： | 邹明旭 |
| |
| 作者单位： | 辽阳石油化工高等专科学校化工系, |
| |
| 摘 要： | 以正戊醇和从二羟酸中分离出的戊二酸酐为原料，以硅钨杂多酸为催化剂进行酯化反应，合成戊二酸二正戊酯。考察醇酐比、反应温度、反应时间、催化剂用量、带水剂对酯化反应的影响，确定合成戊二酸二正戊酯的工艺条件：醇酐摩尔比2．5：1、反应温度140℃、反应时间90min、催化剂用量为体系总量的0．22％、甲苯10mL，酯化率达96％。
|
| 关 键 词： | 戊二酸二正戊酯 催化合成 酯化 硅钨杂多酸 催化剂 |
| 修稿时间： | 2000年12月18 |
Catalytic Synthesis of Diamyl Glutarate with Silicotungstic Acid |
| |
| Zou Mingxu.Catalytic Synthesis of Diamyl Glutarate with Silicotungstic Acid[J].Advances in Fine Petrochemicals,2001,2(1):4-6. |
| |
| Authors: | Zou Mingxu |
| |
| Abstract: | The diamyl glutarate was synthesized by esterification of n- amyl alcohol and glutaric anhydride separated from dicarboxylic acid by catalysis of silicotungstic acid. The effects of molar ratio of alcohol/anhydride, the reaction temperature, the reaction time and the amount of the catalyst used were investigated. The conditions of synthesis were determined as follows; molar ratio of alcohol/anhydride 2. 5:1, reaction temperature 140 C, reaction time 90 min, catalyst amount 0. 22% (based on the total mass of reaction system), toluene 10 mL. The esterification rate of the above reaction was up to 96%. |
| |
| Keywords: | diamyl glutarate synthesis esterification silicotungstic acid catalyst |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
