n-Pentane Hydroisomerization on Pt Containing HZSM-5, HBEA and SAPO-11 |
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Authors: | Carmen M. López Yajaira Guillén Luis García Luis Gómez Ángel Ramírez |
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Affiliation: | (1) Facultad de Ciencias, Escuela de Química, Centro de Catálisis, Petróleo y Petroquímica,, Universidad Central de Venezuela, Apartado 47102, Caracas, 1020-A, Venezuela;(2) Facultad de Ingeniería, Escuela de Ingeniería Química, Universidad Central de Venezuela, Apartado 48057, Caracas, 1020-A, Venezuela |
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Abstract: | Hydroisomerization of n-pentane over platinum promoted acids zeolites was studied. The effect of structure and acidity of the support was investigated at atmospheric pressure between 250 and 400 °C. Pt/HDBEA catalyst showed the best performance at 300 °C with high activity and selectivity to isopentane, due to its structure and a proper balance between acid and metallic sites. This catalyst has a high catalytic stability and regeneration under air flow after deactivation by coking, restores its activity and selectivity. |
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Keywords: | n-Pentane Hydroisomerization Supported-metal catalysts Zeolites |
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