Degradation of toluene and acetaldehyde with Pt-loaded TiO2 catalyst and parabolic trough concentrator

Photocatalytic degradation of volatile organic compounds (VOCs) with Pt-loaded TiO₂ was analyzed at elevated temperatures in the laboratory experiments (40–190 °C) and in the field experiments (30–230 °C). The temperature of catalyst coated on the sunlight receiver was easily elevated to around 200 °C by parabolic trough concentrator (1 m × 1 m). When gaseous toluene (15 ppm) or acetaldehyde (400 ppm) was passed through the reactor, 79% of toluene or 93% of acetaldehyde was removed continuously. In the similar condition, bare TiO₂ was rapidly deactivated by the formation of byproducts. The combination of sunlight concentrator and Pt–TiO₂ catalyst exhibited the enhancement of complete degradation of VOCs, the inhibition of deactivation, and the reactivation of photocatalyst. The contributions of photocatalytic and catalytic activities of Pt–TiO₂ were analyzed by using UV lamp and electric heater. Acetaldehyde is thermocatalytically degraded by photodeposited Pt on TiO₂ at 70–190 °C without UV irradiation, however the UV irradiation is necessary for the complete oxidation of acetaldehyde into CO₂. It is inferred that the degradation of VOCs is enhanced by the combined effect of Pt thermocatalyst and Pt–TiO₂ photocatalyst.