| 聚三烯丙基异氰尿酸酯的合成研究 |
| |
| 引用本文： | 赵小平,李绍文,杨军,丁向东,尤裕如.聚三烯丙基异氰尿酸酯的合成研究[J].热固性树脂,2002,17(4):8-9,17. |
| |
| 作者姓名： | 赵小平 李绍文 杨军 丁向东 尤裕如 |
| |
| 作者单位： | 安徽省化工研究院,安徽合肥,230041 |
| |
| 摘 要： | 采用卤代烃为溶剂和调聚剂,在引发剂存在下,使三烯丙基异氰尿酸酯(TAIC)预聚,制备了一种新型的热固性树脂聚三烯丙基异氰尿酸酯(P-TAIC),其溴值为100g～140g/g,软化点大于200℃。讨论了引发剂、溶剂、单体浓度对预聚反应的影响,测定了预聚反应的平均转化率约为40%,考察了未聚合单体的循环使用情况。
|
| 关 键 词： | 三烯丙基异氰尿酸酯 聚三烯丙基异氰尿酸酯 预聚合 平均转化率 |
| 文章编号： | 1002-7432(2002)04-0008-02 |
RESEARCH ON SYNTHESIS OF POLY (TRIALLYL ISOCYANURATE) |
| |
| Abstract: | Halogenated hydrocarbons being used as solvents and telogens,in the presence of an initiator,a new type of thermosetting resin,poly(triallyl isocyanurate)(P-TAIC) was manufactured by pre-polymerization or telomerization of triallyl isocyanurate(TAIC).The bromine value of P-TAIC was 100～140 g/100 g and softening point was over 200℃.Effect of the initiators,the solvents and the concentration of the monomer on the pre-polymerization were discussed.It was measured that average conversion ratio of pre-polymerization was approximately 40%.Recycle of the unreacted monomer was also tested. |
| |
| Keywords: | Poly (triallyl isocyanurate) Triallyl isocyanurate Pre-polymerization telomerization Average conversion ratio |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
