| D_3-三高立方烷亚甲基上引入硝基的新方法 |
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| 引用本文： | 管晓培,阎红.D_3-三高立方烷亚甲基上引入硝基的新方法[J].北京工业大学学报,1997,23(2):99-101. |
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| 作者姓名： | 管晓培 阎红 |
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| 作者单位： | 北京理工大学化工与材料学院 |
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| 摘 要： | 报道了一种在D_(3-)三高立方烷亚甲基上引入硝基的新方法.应用改进的维克托-迈耶反应,成功地将D_(3-)三高立方烷-4,7-二醇(1)最终转化为4,7-二硝基D_(3-)三高立方烷(3);将原有方法的五步反应缩短为两步反应,并将总得率由低于15%提高到近30%.
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| 关 键 词： | 硝基 亚甲基 三高立方烷 维克托 迈耶反应 |
A New Method for Introducing Nitro Group into the Secondary Carbons of D3-Trishomocubane |
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| Guan Xiaopei Yu Yong Zhong.A New Method for Introducing Nitro Group into the Secondary Carbons of D3-Trishomocubane[J].Journal of Beijing Polytechnic University,1997,23(2):99-101. |
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| Authors: | Guan Xiaopei Yu Yong Zhong |
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| Abstract: | A new method for introducing nitro group into the secondary carbons of D3-trishomocubane is reported. D3-Trishomocubane-4,7-diol(1) was successfully converted into 4,7-dinitro-D3-trishomocubane (3) by modified Victor-Mayer Reaction. The total yield was increased from 15% to 30% while the previous required 5 steps was reduced to 2 steps. |
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| Keywords: | nitro methylene trishomocubane Victor-Mayer reaction |
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