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双施主掺杂对高居里点PTC陶瓷性能的影响
引用本文:郝永德,钟海波,熊眩,龚树萍. 双施主掺杂对高居里点PTC陶瓷性能的影响[J]. 电子元件与材料, 2005, 24(10): 45-47
作者姓名:郝永德  钟海波  熊眩  龚树萍
作者单位:华中科技大学电子科学与技术系,湖北,武汉,430074;华中科技大学电子科学与技术系,湖北,武汉,430074;华中科技大学电子科学与技术系,湖北,武汉,430074;华中科技大学电子科学与技术系,湖北,武汉,430074
摘    要:在分别研究了Nb5+、Y3+掺杂对高温PTC陶瓷性能的影响后,得出结果:Y3+既可作为施主,又可起受主作用,还可以提高升阻比;Nb5+主要是起施主作用,但可以抑制Pb的挥发。为了能够使高温PTC陶瓷整体性能提高,因此结合Nb5+、Y3+各自的优点,用正交法对高温PTC陶瓷进行了双施主掺杂配方的试验,优选了最佳配方:Nb5+应该控制在0.06~0.08之间,Y3+控制在0.08~0.12之间较好。

关 键 词:电子技术  BaTiO3系PTC陶瓷  高居里点  双施主掺杂  铅挥发
文章编号:1001-2028(2005)10-0045-03
收稿时间:2005-04-25
修稿时间:2005-04-25

Effect of Double Donors Doping on BaTiO3-based High Curie Point PTC Ceramics
HAO Yong-de,ZHONG Hai-bo,XIONG Xuan,GONG Shu-ping. Effect of Double Donors Doping on BaTiO3-based High Curie Point PTC Ceramics[J]. Electronic Components & Materials, 2005, 24(10): 45-47
Authors:HAO Yong-de  ZHONG Hai-bo  XIONG Xuan  GONG Shu-ping
Affiliation:Dept of Electronic Science and Technology, Huazhong University of Science and Technology, Wuhan 430074, China
Abstract:The effect of Nb5+、Y3+ donor on the properties of high Curie point PTC ceramics was studied and obtained results are found that Y3+ acts not only as a donor,but also as an acceptor,and can also increase the ratio of ρmax/ρmin;and Nb5+ acts mainly as a donor,but it can decrease the lead volatility.In order to improve the properties of high Curie point PTCR,the Nb5+ and Y3+ donors are doped,and the optimum amount is found that Nb5+ should be controlled in 0.06~0.08,Y3+ in 0.08~0.1.
Keywords:electronic technology   BaO3-basTied PTC ceramics   Curie point   double-donor doping   lead volatility
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