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相转移催化氧化体系在燃料油脱硫中的应用
引用本文:李岚,张海燕,刘倩倩,杨阳.相转移催化氧化体系在燃料油脱硫中的应用[J].化工科技,2011,19(1):61-64.
作者姓名:李岚  张海燕  刘倩倩  杨阳
作者单位:东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆,163318
摘    要:介绍了以过氧化氢为氧化荆的相转移催化氧化脱硫研究现状.对过氧化氢/有机酸/季铵盐体系、过氧化氢/杂多酸/季铵盐体系和过氧化氢/合成相转移催化剂体系在脱除燃料油中噻吩、苯并噻吩、二苯并噻吩等方面的应用作了综述.指出了过氧化氢/合成相转移催化剂体系是燃料油深度脱硫的一个重要研究方向.

关 键 词:相转移  催化氧化  燃料油  脱硫  过氧化氢

Applications of phase transfer catalytic oxidation system in the desulfuration of fuel oil
LI Lan,ZHANG Hai-yan,LIU Qian-qian,YANG Yang.Applications of phase transfer catalytic oxidation system in the desulfuration of fuel oil[J].Science & Technology In Chemical Industry,2011,19(1):61-64.
Authors:LI Lan  ZHANG Hai-yan  LIU Qian-qian  YANG Yang
Affiliation:(Provincial Key Laboratory of Oil and Gas Chemical Technology,College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,China)
Abstract:Present situation of research on the phase transfer catalytic oxidative desulfuration employing hydrogen peroxide as oxidizing agent was introduced.Usage of hydrogen peroxide/organic acid/quaternary ammonium salt,hydrogen peroxide/heteropolyacid/quaternary ammonium salt and hydrogen peroxide/compound phase transfer catalyst systems in the removal of thiophene,benzothiophene,dibenzothiophene were reviewed.It can be concluded that hydrogen peroxide/compound phase transfer catalyst system is an important direction of research in the deepdesulfurization of fuel oil.
Keywords:Phase transfer  Catalytic oxidation  Fuel oil  Desulfuration  Hydrogen peroxide
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